The Champions League returns this week as PSV Eindhoven take on Union Saint-Gilloise, and you can back our betting tips with this 13/2 bet builder.
It’s that time of year again as the league phase of the Champions League gets underway.
Dutch side PSV host Belgian outfit Union SG in round one.
PSV are currently joint top of the Eredivisie alongside Feyenoord, but have played one game more than their rivals.
Their opponents, meanwhile, are unbeaten after the first seven matches of the Belgian pro league, and also sit top of the tree.
Something will have to give on Tuesday, though.
PSV are 9/10 favourites with football betting sites, while Union SG are priced around 3/1.
There is no historic record to go off, though, with these two sides having never met in a competitive fixture.
The Champions League draw has put them together this year, however, and we cannot wait for Tuesday’s action.
Any moment can be ours 😏#PSVUSG #UCL pic.twitter.com/NkoE7opzZY
— PSV (@PSV) September 16, 2025
PSV Vs Union Saint-Gilloise Betting Tips
- Both Teams To Score – YES @ 4/7
- PSV – Full Time Result @ 9/10
- Over 10 Corners @ 11/10
Both Teams To Score – YES @ 4/7
Our first pick is for both teams to score on Tuesday evening.
PSV and Union SG have both been in good form heading in to this one, topping their respective leagues.
With forwards full of confidence and eager to perform on the biggest stage, we expect to see both sides get on the scoresheet at some point.
PSV – Full Time Result @ 9/10
Next, we are backing hosts PSV to get the job done and secure a hard-fought victory.
The Dutch outfit enter this one as favourites, and while we don’t think there’s an awful lot to choose between these tow sides, we do think home advantage could prove enough to make the difference.
As a result, our pick is for PSV to take three points from Tuesday’s round one tie.
Over 10 Corners @ 11/10
And finally, we are predicting at least 11 corners from the match.
Both sides are evenly balanced, and so should expect periods of dominance.
With neither side expected to have full control, an end-to-end game is likely, which may lead to more corners as both sides test each other out and try to create set-piece opportunities.
Back Our PSV Vs Union Saint-Gilloise Betting Tips: 13/2 Champions League Bet Builder
You can back any of these three tips individually, or combine them in to a 13/2 Champions League Bet Builder.
Doing so means that placing a stake of £10 will return £75.

PSV Vs Union Saint-Gilloise Betting Odds
| Match Result | Odds |
| PSV | 9/10 |
| Draw | 27/20 |
| Union SG | 3/1 |
| Player to Score at Any Time | Odds |
| Ricardo Pepi | 6/5 |
| Alassane Plea | 11/8 |
| Myron Boadu | 11/8 |
| Couhaib Driouech | 7/4 |
| Ivan Perisic | 7/4 |
| Dennis Man | 2/1 |
| Christian Makate | 21/10 |
| Mohammed Fuseini | 21/10 |
| Noah Fernandez | 21/10 |
| Paul Wanner | 21/10 |